Mechanistic investigation of cyclic ketene acetal radical ring-opening homo- and co-polymerization and preparation of PEO graft copolymers with tunable composition

Autor:	Yifeng Du, Yuhui Du, Stefano Lazzari, Tom Reimers, Rupert Konradi, Thomas W. Holcombe, E. Bryan Coughlin
Rok vydání:	2022
Předmět:	Polymers and Plastics Organic Chemistry Bioengineering Biochemistry
Zdroj:	Polymer Chemistry. 13:5829-5840
ISSN:	1759-9962 1759-9954
DOI:	10.1039/d2py00986b
Popis:	Radical ring-opening polymerization of cyclic ketene acetals (CKAs) led to homogeneous ester insertion during semi-batch reactions with N-vinyl pyrrolidone (NVP). Investigation of CKA radical transfer allowed for CKA–NVP graft copolymer preparation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::188e7a5bedd92c1801fc1d4610ec08fe https://doi.org/10.1039/d2py00986b Zobrazit plný text záznamu