[Pd(acac)(MeCN)2]BF4: air-tolerant, activator-free catalyst for alkene dimerization and polymerization

Autor:	Pavel A. Abramov, D. S. Suslov, M. V. Bykov, V. S. Tkach, I.A. Ushakov, V.K. Voronov, M.V. Pahomova
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Chemistry Alkene General Chemical Engineering General Chemistry Photochemistry Catalysis Styrene chemistry.chemical_compound Polymerization Activator (phosphor) Polymer chemistry Density functional theory Norbornene
Zdroj:	RSC Advances. 5:104467-104471
ISSN:	2046-2069
DOI:	10.1039/c5ra24591e
Popis:	[Pd(acac)(MeCN)2]BF4 has been observed to catalyze selective substituted styrene dimerization and addition norbornene polymerization. Theoretical calculations based on BP86 density functional theory have been carried out to clarify the precatalyst activation mechanism.
Databáze:	OpenAIRE
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