Iodination of aryl amines in a water-paste form via stable aryl diazonium tosylates

Autor:	Ki-Whan Chi, Elena A. Krasnokutskaya, Dmitry A. Gorlushko, Bong Seong Go, Ho Yun Hwang, Victor D. Filimonov, Eun Hye Cha, Nadya I. Semenischeva
Rok vydání:	2008
Předmět:	Reaction conditions chemistry.chemical_compound Chemistry Aryl Organic Chemistry Drug Discovery Nano Halogenation Organic chemistry Biochemistry Environmentally friendly
Zdroj:	Tetrahedron Letters. 49:1080-1082
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2007.11.192
Popis:	The diazotization of aryl amines at room temperature in paste form with NaNO 2 , p -TsOH and a small amount of water, followed by treatment with KI provides a new, simple, and effective route for the preparation of various aryl iodides. The water-paste and strong acid-free reaction conditions are environmentally friendly and compatible with acid-sensitive functional groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::18880e72f1f8e0f624c087dc35ed3168 https://doi.org/10.1016/j.tetlet.2007.11.192 Zobrazit plný text záznamu Full Text from ScienceDirect