Low-frequency infra-red studies (200–500 cm−1) on complexes containing the (Mo6Cl8)4+ and (W6Cl8)4+ cores

Autor: R. S. Nyholm, D. L. Kepert, Robin J. H. Clark, G.A. Rodley
Rok vydání: 1966
Předmět:
Zdroj: Spectrochimica Acta. 22:1697-1700
ISSN: 0371-1951
DOI: 10.1016/0371-1951(66)80214-x
Popis: The infra-red active metal-chlorine vibrational modes of compounds containing the (Mo6Cl8)4+ and (W6Cl8)4+ cores have been studied above 200 cm−1. Two bands associated with vibrations of the cage are observed in all cases, and the correlation between their energies and the presence of other ligands is discussed.
Databáze: OpenAIRE