Autor:	O. M. Aliev, V. A. Kasumov, R. M. Agaeva
Rok vydání:	2002
Předmět:	Inorganic Chemistry Crystallography Chemistry General Chemical Engineering Lattice (order) X-ray crystallography Inorganic chemistry Materials Chemistry Metals and Alloys Orthorhombic crystal system Crystal structure Chemical synthesis Solid solution
Zdroj:	Inorganic Materials. 38:645-646
ISSN:	0020-1685
DOI:	10.1023/a:1016219820562
Popis:	Using the sealed-ampule technique, the compounds Cu2LnSb3S7 (Ln = La, Nd) were synthesized for the first time. Cu2LaSb3S7 and Cu2NdSb3S7 crystallize in the orthorhombic system and have identical crystal structures. The lattice parameters of Cu2LaSb3S7 are a = 14.43 A, b = 21.42 A, and c= 3.97 A those of Cu2NdSb3S7 area = 14.463 A, b= 21.404 A, and c = 3.962 A. Between 1080 and 1095 K, both compounds decompose to form disordered CuSbS2–LnSbS3 solid solutions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::186f81b371685dbd5c66575c0b44267d https://doi.org/10.1023/a:1016219820562 Zobrazit plný text záznamu Full text from SpringerLink