Electrochemical performance of sulfide solid electrolyte Li10GeP2S12 synthesized by a new method
| Autor: | Jing Hu, Lili Zhao, Qing Zhang, Yongping Zhu, Ying Chu, Weihua Wan |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Materials science Sulfide Mechanical Engineering 02 engineering and technology Activation energy Electrolyte Conductivity 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Electrochemistry 01 natural sciences Lithium-ion battery 0104 chemical sciences chemistry Chemical engineering Mechanics of Materials Electrode General Materials Science 0210 nano-technology Ball mill |
| Zdroj: | Materials Letters. 248:153-156 |
| ISSN: | 0167-577X |
| DOI: | 10.1016/j.matlet.2019.04.022 |
| Popis: | Solid electrolyte Li10GeP2S12 (LGPS) was successfully synthesized by optimizing the mechanical ball milling process and subsequent heat treatment process using Li, Ge, P and S as raw materials. The synthesis method has the advantages of low cost, simple process, short cycle and high efficiency. The synthesized LGPS possesses regular morphology and uniform particle distribution without agglomeration. Simultaneously, it presents a wide electrochemical voltage window of over 6.0 V (vs. Li+/Li), a low activation energy Ea of 25.5 kJ mol−1 and the room temperature conductivity σLi of 3.27 × 10−3 S cm−1. The synthesized LGPS solid electrolyte exhibits good electrochemical stability and compatibility with lithium metal electrodes, making it possible to apply in all solid state batteries. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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