Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc
| Autor: | Muge Shele, Menghe Baiyin, Xin-Yu Tian |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Solvothermal synthesis chemistry.chemical_element Zinc Photoelectric effect Condensed Matter Physics Electronic Optical and Magnetic Materials Ion Inorganic Chemistry Solvent Transition metal Antimony chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Amine gas treating Physical and Theoretical Chemistry |
| Zdroj: | Journal of Solid State Chemistry. 302:122401 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2021.122401 |
| Popis: | Three antimony chalcogenides containing transition metal zinc ions were successfully prepared by solvent method, namely, [Zn(tren)2H]SbSe4 (1) [tren = tris (2 - aminoethyl) amine) ], [Ni(1, 2-dap)3]2Zn(1, 2-dap)Sb2Se8 (2) (1, 2 - dap = 1, 2 - diaminopropane) and Rb2ZnSb4S8 (3). Interestingly, the Zn2+ ion in compound 1 is a trigonal-bipyramidal structure, while in compounds 2 and 3 it is a tetrahedral structure. The optical and photoelectric properties of compounds 1–3 were studied. In addition, the magnetic of compound 2 was studied. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect