Kinetics and mechanism of the methanolysis of acetylcobalt tetracarbonyl

Autor:	Judit Sóvágó, Attila Sisak, László Markó, Ferenc Ungváry
Rok vydání:	1994
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Mechanism (philosophy) Kinetics Materials Chemistry Nucleophilic substitution Organic chemistry Methanol Acid–base reaction Physical and Theoretical Chemistry Carbon monoxide Catalysis
Zdroj:	Inorganica Chimica Acta. 227:297-300
ISSN:	0020-1693
Popis:	The rate of acetylcobalt tetracarbonyl methanolysis between 40 and 60 °C is first-order with respect to the acetylcobalt tetracarbonyl concentration and independent of the carbon monoxide concentration. The reaction is susceptible to both acid and base catalysis. Nucleophilic substitution of Co(CO) 4 on the acyl carbonyl-carbon by methanol is the most probable pathway.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::183a43cc2f88aa2ad944e93c6ba7a582 https://doi.org/10.1016/0020-1693(94)04211-x Zobrazit plný text záznamu