Overdoping: a suitable method to get crack-free YBa2Cu3O7-δfilms

Autor: A. K. Sarin Kumar, Hideomi Koinuma, Megumi Kawasaki
Rok vydání: 2001
Předmět:
Zdroj: Superconductor Science and Technology. 14:1148-1151
ISSN: 1361-6668
0953-2048
DOI: 10.1088/0953-2048/14/12/336
Popis: One of the problems with the c-axis in-plane aligned YBa2Cu3O7-? films on different substrates is the cracking perpendicular to the c-axis, which should be avoided if such films are to be used for device applications. The devices based on the Josephson plasma phenomenon, which is a phase collective oscillation of the Cooper pair through the insulating barriers of the intrinsic Josephson junctions, requires carrier controlled (Tc = 60?K), c-axis in-plane aligned and crack-free YBa2Cu3O7-? films. Here we propose that overdoping of the YBa2Cu3O7-? films by substituting Ca at the Y site can help to produce crack free, c-axis in-plane aligned films. This would help to anneal the YBa2Cu3O7-? films at a lower oxygen partial pressure than the pristine YBa2Cu3O7-? and thus to obtain the 60?K phase with an elongated c-axis. This is because substantial oxygen incorporation into the films during annealing followed by the compression of the c-axis are the main causes of the crack formation. We designed an experiment to get crack free, 60?K phase YBa2Cu3O7-? films with the c-axis in the substrate plane and we verified our design by fabricating c-axis in-plane aligned (110) oriented Y0.7Ca0.3Ba2Cu3O7-y films on SrTiO3 (110) substrates.
Databáze: OpenAIRE