Preparation and Thermal Performance of Poly(Methyl Methacrylate)/Binary Alkane-Alcohol Organic Eutectic Microcapsules as Phase Change Materials for Cold Storage
| Autor: | Huan Zhi Zhang, Lixian Sun, Gao Ni, Fen Xu, Zhong Cao |
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| Rok vydání: | 2016 |
| Předmět: |
Alkane
chemistry.chemical_classification Materials science Mechanical Engineering Cold storage Emulsion polymerization Condensed Matter Physics Phase-change material Poly(methyl methacrylate) chemistry.chemical_compound chemistry Chemical engineering Mechanics of Materials visual_art Polymer chemistry visual_art.visual_art_medium General Materials Science Thermal stability Methyl methacrylate Eutectic system |
| Zdroj: | Materials Science Forum. 852:614-617 |
| ISSN: | 1662-9752 |
| DOI: | 10.4028/www.scientific.net/msf.852.614 |
| Popis: | In this study, the microcapsules containing binary alkane-alcohol organic eutectic of mixed n-tetradecane and 1-dodecanol (TD-DD) phase change materials as the core and poly (methyl methacrylate)(PMMA) as the shell were prepared by emulsion polymerization reaction. The microcapsules were characterized by using DSC, SEM, FT-IR and TG. The results of DSC test showed that melting and freezing temperatures of the microcapsules are-6.136 °C and 5.203 °C, and total latent heat value are-82.522 J/g and 77.632 J/g, respectively. The SEM and FT-IR analyses indicated that PMMA shell has successfully encapsulated TD-DD. The TD-DD and the microcapsules exhibited in spherical shape. Additionally, the TG test showed that the thermal stability of TD-DD was increased after encapsulation. |
| Databáze: | OpenAIRE |
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