Synthesis, characterization, and reactivity of copper complexes supported by the TPMEN ligand framework
| Autor: | Anusree Mukherjee, Bruce J. Pella, Victoria G. Snider |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Absorption spectroscopy
010405 organic chemistry Ligand Electrospray ionization Quinoline 010402 general chemistry Photochemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Moiety Amine gas treating Reactivity (chemistry) Physical and Theoretical Chemistry Potassium superoxide |
| Zdroj: | Inorganica Chimica Acta. 469:447-452 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2017.09.041 |
| Popis: | Two new Cu(II) complexes supported by nitrogen-rich ligands have been synthesized and characterized by absorption spectroscopy, magnetic moment, and cyclic voltammetry. Complex 1 is supported by the ligand TPMEN (N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) with two amine and three pyridyl nitrogen donors; while 2 is supported by the ligand TQMEN (N,N,N′-tris(2-quinolylmethyl)-N′-methylethylenediamine) where quinoline groups replace the pyridyl groups. Replacing the pyridyl moiety with quinoline has a marked effect on the Cu(II/I) reduction couple. The complexes are capable of reducing superoxide (O2 −) to hydrogen peroxide (H2O2) in the presence of a proton donor. The reaction between potassium superoxide (KO2) and the Cu-complexes was monitored via absorption spectroscopy, and further probed with electrospray ionization mass spectrometry (ESI-MS). Both 1 and 2 depicted evidence of ligand oxidation in mass-spectrometry. |
| Databáze: | OpenAIRE |
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