Polymer electrolytes—relaxation and transport properties
| Autor: | Hans Werner Kammer, Chin Han Chan |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Range (particle radiation) Materials science Ethylene oxide General Chemical Engineering Transport coefficient General Engineering General Physics and Astronomy Salt (chemistry) Thermodynamics Electrochemistry Lithium perchlorate chemistry.chemical_compound chemistry Polymer chemistry Relaxation (physics) General Materials Science Electrical impedance |
| Zdroj: | Ionics. 21:927-934 |
| ISSN: | 1862-0760 0947-7047 |
| DOI: | 10.1007/s11581-014-1256-3 |
| Popis: | Relaxations in polymer electrolytes were studied in poly(ethylene oxide) and epoxidized natural rubbers both filled with lithium perchlorate. Impedance relaxation was investigated over a wide range of salt concentration at room temperature. Imaginary part of impedance as a function of frequency exhibits generally one maximum and one minimum. These two extreme values rule properties in the DC limit. They can be related to transport properties and degree of dissociation. It turns out that DC conductivity is dominantly ruled by transport coefficient. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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