SOME DEUTERIUM KINETIC ISOTOPE EFFECTS: II. α-DEUTERIUM EFFECTS IN THE WATER SOLVOLYSIS OF SOME ALKYL COMPOUNDS

Autor:	J. A. Llewellyn, K. T. Leffek, R. E. Robertson
Rok vydání:	1960
Předmět:	chemistry.chemical_classification Deuterium Computational chemistry Chemistry Organic Chemistry Kinetic isotope effect Organic chemistry General Chemistry Solvolysis Kinetic energy Catalysis Isopropyl Alkyl
Zdroj:	Canadian Journal of Chemistry. 38:1505-1510
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v60-210
Popis:	As an extension of previous work on methyl compounds, α-deuterium kinetic effects have been measured for ethyl, n-propyl, and isopropyl compounds. The effects can be accounted for in terms of current theory but a modification involving intramolecular van der Waals forces seems to provide a more satisfactory description of some of the processes involved in the production of the rate changes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::17c7d957dd944c1723c5c1546bf2fc52 https://doi.org/10.1139/v60-210 Zobrazit plný text záznamu