Physico-chemical studies of polymeric carriers: 2. Molecular mass determination of poly(N-vinylpyrrolidone-co-maleic acid) fractions

Autor: Ferenc Tüdős, Mária Azori, Éva Csákvári
Rok vydání: 1981
Předmět:
Zdroj: Polymer Bulletin. 5:673-677
ISSN: 1436-2449
0170-0839
DOI: 10.1007/bf00255309
Popis: Critical interpretation of the various conceptions concerning the problems in characterization of linear polyelectrolyte type polymers containing maleic acid as a comonomer is given. Proper conditions to avoid the fundamental experimental difficulties are proposed. Our conception is supported by molecular light scattering measurements of hydrolysed, fractionated poly (N-vinylpyrrolidone-co-maleic anhydride) samples. It was found that the problems were eliminated by the reduction of the degree of dissociation of carboxyl groups to a minimum value.
Databáze: OpenAIRE