Photochemically induced reaction between perfluoroacetone and ethane

Autor:	R. H. Knipe, William P. Norris, Alvin S. Gordon, Joseph H. Johnson
Rok vydání:	1975
Předmět:	Inorganic Chemistry chemistry.chemical_compound Trifluoromethyl chemistry Organic Chemistry Photodissociation Physical and Theoretical Chemistry Photochemistry Biochemistry
Zdroj:	International Journal of Chemical Kinetics. 7:15-22
ISSN:	1097-4601 0538-8066
DOI:	10.1002/kin.550070103
Popis:	The gas-phase photolysis of perfluoroacetone in the presence of ethane has been shown to result in the production of significant amounts of 1, 1-bis(trifluoromethyl)propanol-1, (CF3)2(C2H5)COH, and 1, 1, 4, 4-tetrakis(trifluoromethyl)butane-1, 4-diol, (CF3)2C(OH)-CH2CH2C(OH)(CF3)2. A mechanism is presented which accounts for the relative rates of formation of these products at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::17b1a7fc71dc950c74e8f00aa7398e19 https://doi.org/10.1002/kin.550070103 Zobrazit plný text záznamu Plný text