Popis: |
Many researchers have produced various results for the mechanism of the metal-insulator transition (MIT) of VO 2 . This seems to be because of the influence of various VO x phases in the sample thin-film. VO x has many phases, and VO 2 is in only a small window in the VO x phase diagram. In this work, VO 2 thin films on Al 2 O 3 substrates were prepared by a pulsed laser deposition method, and their I-V properties were measured over a temperature range from 50 K to 300 K. In the thin-films, not only the VO 2 phase, but also at least two other VO x phases were present, including V 2 O 3 and V 5 O 9 . For electrically triggered MIT, a space charge limit current (SCLC) appeared at high voltages while ohmic current appeared at low voltages, and MIT occurred when the space charge density became greater than the critical carrier density, nc. This is a current-driven device, basically, because MIT occurs after the charge carrier density, which is injected from the electrode becomes higher than nc. The switching time, which is the time for the whole sample to transition from insulator to metal because of bias application, depends on the charge carrier mobility in the insulator state. The switching speed of VO 2 due to electrical triggering must be slower than that of optical triggering because the mobility of the charge carrier in the insulating state is only 0.5 cm 2 / V •s. For a simple two terminal model, the switching speed is proportional to the square of the length between the two electrodes and the mobility of the charge carrier, and inversely proportional to the voltage. Therefore, a proper switching speed can be designed for one’s use if the appropriate material and dimension of the device are used. |