One-Carbon Homologation of Primary Alcohols and the Reductive Homologation of Aldehydes Involving a Jocic-Type Reaction

Autor:	Manoj K. Gupta, Zhexi Li, Timothy S. Snowden
Rok vydání:	2015
Předmět:	Primary (chemistry) chemistry Organic Chemistry chemistry.chemical_element Organic chemistry Physical and Theoretical Chemistry Carbon
Zdroj:	European Journal of Organic Chemistry. 2015:7009-7019
ISSN:	1434-193X
Popis:	(Trichloromethyl)carbinols, which are formed in one operation from either alcohols or aldehydes, can be converted into primary alcohols in a Jocic-type reaction involving LiBH4. The net result is a convenient two-step, one-carbon homologation of primary alcohols or a reductive one-carbon homologation of aldehydes featuring a broad substrate scope. The method is step-economical, and it nicely complements established one-carbon homologation strategies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::17a191773e5dd395a8fd276623d70eb1 https://doi.org/10.1002/ejoc.201501089 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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