ChemInform Abstract: Hydroformylation of Olefins in the Presence of Heterogeneous Cobalt Carbonyl Catalysts

Autor:	N. A. Pritula, O. L. Butkova, S. M. Loktev, G. A. Korneeva
Rok vydání:	1988
Předmět:	inorganic chemicals Denticity Silica gel Ligand chemistry.chemical_element General Medicine Catalysis chemistry.chemical_compound chemistry Polymer chemistry Chemical binding Selectivity Cobalt Hydroformylation
Zdroj:	ChemInform. 19
ISSN:	0931-7597
Popis:	1. The introduction of silica gel into a homogeneous catalytic system for the hydroformylation of olefins containing hydrocarbonyltributylphosphinecobalt leads to the partial deactivation of the catalyst and a decrease in the selectivity due to binding of cobalt and the ligand by the surface hydroxyl groups. 2. The chemical binding of the silica gel OH group by the bidentate silylphosphine ligands permits modification of cobalt hydrocarbonyl to give a heterogeneous selective and stable catalyst for the hydroformylation of propylene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::179de009c1b295d1c34a4ef7f7817e1a https://doi.org/10.1002/chin.198808091 Zobrazit plný text záznamu Plný text