Crown-annelated tetrathiafulvalenes: synthesis of new functionalised derivatives and spectroscopic and electrochemical studies of metal complexation
| Autor: | Adrian J. Moore, Javier Garín, V. Morisson, Michael C. Petty, John N. Moore, Martin R. Bryce, María Savirón, Ronald E. Hester, Jean-Michel Raoul, Igor K. Lednev, Leonid M. Goldenberg, Reinhold Dieing |
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| Rok vydání: | 1996 |
| Předmět: | |
| Zdroj: | J. Chem. Soc., Perkin Trans. 2. :1587-1593 |
| ISSN: | 1364-5471 0300-9580 |
| DOI: | 10.1039/p29960001587 |
| Popis: | Synthetic routes to the first unsymmetrical annelated tetrathiafulvalene–S2O4 crowns are reported; the methodology is versatile, affording the parent system 8, functionalised derivatives 6, 7 and 9–12, and amphiphilic derivatives 6 and 13. UV–VIS spectroscopic studies of metal binding (Na+, Ag+ and Ba2+) to the crown–TTF systems 8 and 13, and the bis(crown)–TTF 14 have been performed in solution, and stability constants have been calculated. The data establish that for the crown compounds 8 and 13 1 : 1 complexes are formed, whereas for the bis(crown) compound 14 both 1 : 1 [14(Na+)] and 1 : 2 [14(Na+)2] complexes are formed. Solution electrochemical studies reveal that metal complexation to the crown unit leads to a small anodic shift in the first oxidation potential of the TTF system. Langmuir–Blodgett films of amphiphilic compound 13 have been assembled on solid substrates by Y-type deposition. |
| Databáze: | OpenAIRE |
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