Synthesis of Tricyclic Isoquinoline Derivatives via Palladium- Catalyzed Tandem Reactions of 2,7-Alkadiynylic Carbonates with 2,3-Allenyl Sulfamides

Autor:	Chunling Fu, Wangteng Wu, Shengming Ma, Shihua Song, Xin Huang
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Tandem 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Organic chemistry Isoquinoline Tricyclic Palladium
Zdroj:	Advanced Synthesis & Catalysis. 358:2791-2805
ISSN:	1615-4150
DOI:	10.1002/adsc.201600406
Popis:	The palladium-catalyzed tandem reactions of 2,7-alkadiynylic carbonates with 2,3-allenyl sulfamides for the syntheses of fused tricycles such as 1,3,6,7,8,9-hexahydrofuro[3,4-h]isoquinoline, 2,3,6,7,8,9-hexahydro-1H-pyrrolo[3,4-h]isoquinoline, and 2,3,4,7,8,9-hexahydro-1H-cyclopenta[h]isoquinoline derivatives have been developed. A mechanism has been proposed based on the isolation of a by-product.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::178c80b95943d1b1115c33555331bfa9 https://doi.org/10.1002/adsc.201600406 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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