Determination of Nitrate in the Presence of Nitrite in Natural Waters by Flow Injection Analysis with a Non-Quantitative On-Line Cadmium Reductor
| Autor: | J. P. Riley, Su-Cheng Pai |
|---|---|
| Rok vydání: | 1994 |
| Předmět: |
Flow injection analysis
Cadmium Reducing agent Health Toxicology and Mutagenesis Natural water Inorganic chemistry Public Health Environmental and Occupational Health Soil Science chemistry.chemical_element Pollution Analytical Chemistry chemistry.chemical_compound chemistry Nitrate Environmental Chemistry Nitrite Derivatization Waste Management and Disposal Water Science and Technology |
| Zdroj: | International Journal of Environmental Analytical Chemistry. 57:263-277 |
| ISSN: | 1029-0397 0306-7319 |
| DOI: | 10.1080/03067319408027460 |
| Popis: | Several analytical problems in the determination of nitrate using flow injection analysis (FIA) coupled with an on-line Cd reductor have been studied. It was found difficult to prepare a nearly 100%-efficient copperized Cd reductor which maintains its efficiency over a lengthy period. Instead, the use of a narrow and lower efficiency Cd coil is recommended because it is more stable and therefore more suitable for FIA. Since the conversion of nitrate to nitrite is not quantitative, results for nitrate tend to be over-estimates when nitrite is also present. This problem has been solved by using a simple correction scheme to compensate for the effect of nitrite, thus enabling the correct nitrate concentration to be evaluated. The validity of the correction procedure has been confirmed by running a series of known standards containing both nitrate and nitrite with three types of FIA manifolds. Results for nitrate were accurate for fresh and saline waters even when the co-existing nitrite concentratio... |
| Databáze: | OpenAIRE |
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