Reactivity and Mechanistic Studies of the Reactions of Chlorodiphenylphosphine and Its Oxide with Methyl Glyoxylate, Glyoxylate Oximes, and Methyl Cyanoformate

Autor:	Carlos F. R. A. C. Lima, Ivo E. Sampaio-Dias, Xerardo García-Mera, Carlos Sousa, José E. Rodríguez-Borges
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Reaction mechanism chemistry Diphenylphosphine Chlorodiphenylphosphine Oxide Glyoxylate cycle Organic chemistry Methyl cyanoformate Reactivity (chemistry) General Chemistry Derivative (chemistry)
Zdroj:	Heteroatom Chemistry. 26:249-256
ISSN:	1042-7163
DOI:	10.1002/hc.21255
Popis:	In this work, we describe the reactivity of chlorodiphenylphosphine and its oxide, as well as diphenylphosphine, with some glyoxylate derivative systems: methyl glyoxylate, methyl or 8-phenylneomenthyl glyoxylate oximes, and methyl cyanoformate. By analyzing the reactions outcomes and with the aid of computational chemistry, we propose some reaction mechanisms and molecular rearrangements.
Databáze:	OpenAIRE
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