Study of diallylisophthalate polymerization by DSC and PMR methods

Autor:	I.K. Mosevich, M.L. Shevchenko, A.G. Boldyrev, V. M. Denisov, I.L. Ushakova, M.F. Lebedeva, O. A. Pisarev, I.A. Arbuzova, A. I. Kol'tsov, Ye.V. Kuvshinskii
Rok vydání:	1989
Předmět:	Kinetic chain length Chain-growth polymerization Polymerization Bulk polymerization Chemistry Polymer chemistry Radical polymerization technology industry and agriculture General Engineering Precipitation polymerization Cationic polymerization Chain transfer
Zdroj:	Polymer Science U.S.S.R.. 31:156-163
ISSN:	0032-3950
DOI:	10.1016/0032-3950(89)90364-x
Popis:	The radicapolymerization of diallylisophthalate was studied, in the presence of three initiators, with continuous temperature change up to 200°C. Three heat-evolution peaks were observed, connected with initiator decomposition. Monomer consumption and double bond conversion were followed in the course of the polymerization. Changes in the content of double bonds and in the number of inter-crosslink units were determined from DSC and PMR data. The polymerization process consists of two stages: quasilinear polymerization and structurization. Monomer is consumed to produce the primary polymer chains, whereas structurization is characterized by the formation of secondary polymer chains by was of double bond consumption.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1785397e98b59be17c3e7fe07c318994 https://doi.org/10.1016/0032-3950(89)90364-x Zobrazit plný text záznamu