Synthesis, characterization and photochromic studies in film of heterocycle-containing spirooxazines

Autor:	Jiben Meng, Hua-Ming Huang, † Ting-Feng Tan, Pei-Li Chen
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Absorption spectroscopy Organic Chemistry Polymer Photochemistry Biochemistry Characterization (materials science) chemistry.chemical_compound Fatigue resistance Photochromism chemistry Drug Discovery Flash photolysis Continuous irradiation Merocyanine
Zdroj:	Tetrahedron. 61:8192-8198
ISSN:	0040-4020
DOI:	10.1016/j.tet.2005.06.057
Popis:	A series of novel heterocycle-containing spirooxazines have been designed and synthesized, and their photochromic properties were investigated under flash photolysis and continuous irradiation in particular regard to the fatigue resistance, the lifetime of the colored merocyanine form in various solutions and polymers. Especially, the characteristics of two UV-sensitive spirooxazines dispersed polymethylmethacrylate thin-films were extensively studied. Detailed studies showed that general significant shifts in the λ max of the absorption spectra of the open forms, interesting fatigue resistances and emission fluorescene properties were observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::177ad8f8cb91e077273d79a02933f34b https://doi.org/10.1016/j.tet.2005.06.057 Zobrazit plný text záznamu Full Text from ScienceDirect