Pd/TiO2 Washcoated Cordierite Minimonoliths for Hydrodechlorination of Light Organochlorinated Compounds

Autor:	C. Montes de Correa, Alba Nelly Ardila, Miguel Ángel Martínez, Carlos González, Gustavo Fuentes-Zurita
Rok vydání:	2007
Předmět:	Materials science Chemical engineering Elemental analysis General Chemical Engineering Slurry engineering Mineralogy Cordierite General Chemistry Microreactor engineering.material Industrial and Manufacturing Engineering Catalysis
Zdroj:	Industrial & Engineering Chemistry Research. 46:7961-7969
ISSN:	1520-5045 0888-5885
DOI:	10.1021/ie070713r
Popis:	Pd over TiO2 (sol−gel and Hombikat uv-100) slurries with and without binders have been deposited on square-channel cordierite honeycombs, and vibration, heat, and abrasion resistance of washcoated minimonoliths have been evaluated. Activity tests were carried out in a microreactor operated at differential conditions. Fresh and used catalyst samples were characterized by elemental analysis, XRD, BET, H2-chemisorption, H2-TPR, NH3-TPD, UV−vis, and SEM in order to assess not only the properties but also the homogeneity of catalyst layers. The results show that washcoat loading and catalytic performance are affected by the kind of binder used in the slurry. Washcoat differences are also found regarding vibration, heat, and abrasion resistance.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::176f99904660dcad579bfe2584d58fa1 https://doi.org/10.1021/ie070713r Zobrazit plný text záznamu