Effect of the amounts and proportions of active components on the activity and selectivity of a catalyst for vinyl acetate synthesis by gas-phase ethylene acetoxylation

Autor:	P. S. Voskanyan
Rok vydání:	2010
Předmět:	inorganic chemicals Ethylene organic chemicals Potassium chemistry.chemical_element Catalysis Vinyl acetate synthesis chemistry.chemical_compound chemistry Vinyl acetate Organic chemistry Composition (visual arts) Selectivity Palladium
Zdroj:	Catalysis in Industry. 2:167-172
ISSN:	2070-0555 2070-0504
Popis:	The activity, selectivity, and service life of a palladium-, gold-, and potassium acetate-containing catalyst for vinyl acetate (VA) synthesis are reported as a function of the catalyst composition. Equations relating these performance parameters to the percentage of each component are suggested. General relation-ships between the catalytic activity and the component contents are established for optimization of the catalyst composition. These relationships have been validated by bench tests. The average activity of the 1.5% Pd + 0.75% Au + 5.0% KOAc catalyst is 700 (g VA)/(l Cat h), and its ethylene-to-VA conversion selectivity is 93–95%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::176a7c731e094c491313df354f4d6b64 https://doi.org/10.1134/s2070050410020121 Zobrazit plný text záznamu Full text from SpringerLink