Serinolic amino-s-triazines: iterative synthesis and rotational stereochemistry phenomena as N-substituted derivatives of 2-aminopropane-1,3-diols

Autor:	Flavia Popa, Pedro Lameiras, Mircea Darabantu, Camelia Berghian, Ioan Silaghi-Dumitrescu, Constantin Bele, Nelly Plé, Ionut Cadis, Marijana Fazekas, Monica Pintea
Rok vydání:	2008
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Computational chemistry Dendrimer Organic Chemistry Drug Discovery Cyanuric chloride Nuclear magnetic resonance spectroscopy Biochemistry Amination
Zdroj:	Tetrahedron. 64:8851-8870
ISSN:	0040-4020
Popis:	The iterative synthesis of 2,4,6-triamino-s-triazines (melamines), precursors and dendritic structures, by amination of cyanuric chloride with C-1 versus C-2-substituted 2-aminopropane-1,3-diols (serinols), is comparatively examined. The stereochemistry of the resulting serinolic amino-s-triazines, issued from the restricted rotation about the newly created C(s-triazine)–N bonds, is for the first time discussed in terms of (pro)diastereomerism based on DNMR and DFT calculation data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1767f965ace0161aaa585759bfcbef35 https://doi.org/10.1016/j.tet.2008.06.071 Zobrazit plný text záznamu Full Text from ScienceDirect