Polarized fluorescence of monoanions of Zn-octaethylphlorin
Autor: | G. N. Sinyakov, V. N. Knyukshto |
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Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Journal of Applied Spectroscopy. 64:341-344 |
ISSN: | 1573-8647 0021-9037 |
DOI: | 10.1007/bf02675095 |
Popis: | We investigate the luminescent properties (radiation spectrum, polarized spectrum) of the monoanions of Zn-octaethylphlorin, which is an intermediate product of the reduction, reaction of porphyrins. An oscillator model is presented that includes three electronic oscillators, with a long-wave one being oriented perpendicularly to the remaining two. The lifetime of the excited singlet state τ=30±15 nsec is estimated. |
Databáze: | OpenAIRE |
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