Electrogenerated Chemiluminescence of Tris(dibenzoylmethane)phenanthroline Europium(III) as a Light Source: An Application for the Detection of PO43-Based on the Ion Associate Formation of Phosphomolybdic Acid and Malachite Green

Autor:	Toshihiko Imato, Ryoichi Ishimatsu, Eri Kunisawa, Koji Nakano
Rok vydání:	2019
Předmět:	Dibenzoylmethane Phenanthroline chemistry.chemical_element Analytical Chemistry law.invention Absorbance chemistry.chemical_compound chemistry law Phosphomolybdic acid Electrochemiluminescence Malachite green Europium Chemiluminescence Nuclear chemistry
Zdroj:	Analytical Sciences. 35:799-802
ISSN:	1348-2246 0910-6340
Popis:	We demonstrate that electorogenerated chemiluminescence (ECL) of an organometallic Eu(III) complex, tris(dibenzoylmethane)phenanthroline europium(III), whose emission spectra is very sharp with the maximum wavelength of 612 nm, can be used as a light source for the detection of PO43- based on changing the absorbance of the ion associate of malachite green (MG+) and phosphomolybdic acid. The ECL was also applied to measure the absorbance of MG+. With the detection system we established, absorbance up to ∼1.6 with a change of ∼0.1 could be detected.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::17597dadb3d56ccfd201a029c56b414a https://doi.org/10.2116/analsci.19n003 Zobrazit plný text záznamu Full text from SpringerLink