Thermal properties of high quality single crystals of bismuth telluride—Part II: Mixed-scattering model

Autor: Jean-Pierre Fleurial, H. Scherrer, S. Scherrer, L. Gailliard, R. Triboulet
Rok vydání: 1988
Předmět:
Zdroj: Journal of Physics and Chemistry of Solids. 49:1249-1257
ISSN: 0022-3697
DOI: 10.1016/0022-3697(88)90183-7
Popis: From the preceding experimental study on the thermoelectric properties of Bi2Te3, a mixedscattering model was used to fit the sharp variations of the various parameters with stoichiometric deviations. First a one-band model was developed: the Fermi level and the main scattering mechanism were determined and values for the Hall factor, the Lorenz number, the effective mass and the relaxation time constant found for both n- and p-type material. Using a two-band model permitted the fitting of the behaviour of the thermoelectric parameters in the vicinity of the change in type. The optimum Fermi level for the maximum of the figure of merit was found just at the bottom of the conduction band.
Databáze: OpenAIRE