Samarium(II) iodide-induced cascade reaction for tricyclic γ-lactone synthesis from acyclic keto diesters

Autor:	Atsushi Kishida, Hiroto Nagaoka
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Bicyclic molecule Stereochemistry Organic Chemistry Iodide Samarium(II) iodide chemistry.chemical_element Biochemistry Dieckmann condensation Samarium chemistry.chemical_compound chemistry Decalin Cascade reaction Drug Discovery Cis–trans isomerism
Zdroj:	Tetrahedron Letters. 49:6393-6397
ISSN:	0040-4039
Popis:	Cascade reaction involving reductive cyclization, Dieckmann condensation, and lactonization of E- and Z-dimethyl 2-methyl-8-oxoundec-2-enedioates and Z-dimethyl 2-methyl-7-oxodec-2-enedioate with samarium(II) iodide was found to stereospecifically produce cis and trans bicyclo[4.4.0]decane (decalin) ring systems and trans bicyclo[4.3.0]nonan (perhydroindane) ring system each consisting of γ-lactone, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::173fc9e4e5726cdcb8fa5d3f4c5d4197 https://doi.org/10.1016/j.tetlet.2008.08.105 Zobrazit plný text záznamu Full Text from ScienceDirect