Chemiluminescence during the oxidation of histamine by potassium bromate activated with terbium
Autor: | L. A. Fukalova, A. D. Karavaev, G. V. Kosareva, Glyus L. Sharipov |
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Rok vydání: | 1983 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:702-708 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00953460 |
Popis: | 1. We have detected and investigated chemiluminescence (CL) during the oxidation of the biologically active amine, histamine, which can be used for analytical purposes. 2. The primary emitter of the chemiluminescence, which is most probably imidazolylacetaldehyde, is formed in the triplet state with an energy in the range from 2.60 to 3.98 eV. 3. Tb3+ ions do not accelerate the oxidation of histamine but activate the chemiluminescence via an energy transfer mechanism. |
Databáze: | OpenAIRE |
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