Chemiluminescence during the oxidation of histamine by potassium bromate activated with terbium

Autor: L. A. Fukalova, A. D. Karavaev, G. V. Kosareva, Glyus L. Sharipov
Rok vydání: 1983
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:702-708
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00953460
Popis: 1. We have detected and investigated chemiluminescence (CL) during the oxidation of the biologically active amine, histamine, which can be used for analytical purposes. 2. The primary emitter of the chemiluminescence, which is most probably imidazolylacetaldehyde, is formed in the triplet state with an energy in the range from 2.60 to 3.98 eV. 3. Tb3+ ions do not accelerate the oxidation of histamine but activate the chemiluminescence via an energy transfer mechanism.
Databáze: OpenAIRE