Bifurcation in the rotational spectra of nonlinear symmetric triatomic molecules

Autor:	I. M. Pavlichenkov, I. N. Kozin
Rok vydání:	1997
Předmět:	Physics Valence (chemistry) media_common.quotation_subject Triatomic molecule General Physics and Astronomy Inertia Spectral line Nonlinear system Physics::Chemical Physics Microscopic theory Atomic physics Bifurcation Stationary state media_common
Zdroj:	Journal of Experimental and Theoretical Physics. 85:673-681
ISSN:	1090-6509 1063-7761
Popis:	A microscopic theory is proposed for bifurcation in the rotational spectra of nonlinear AB2-type molecules. The theory is based on a study of small-amplitude vibrational and precessional motion near the stationary states of a rotating molecule. Bifurcation leads to the formation of fourfold clusters of levels in the upper parts of the rotational multiplets, disruption of the symmetry of the molecule, and a transition from normal to local valence vibrations. The role of the centrifugal force of inertia in the development of these effects is clarified. Bifurcation and the accompanying phenomena are studied in the hydride molecules H2O, H2S, H2Se, and H2Te using empirical molecular potentials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::173d4284d82cf763cd538f7df9f0238f https://doi.org/10.1134/1.558353 Zobrazit plný text záznamu Plný text ve formátu PDF