The synthesis and molecular structure of η6-carbidohexadecacarbonylhexaruthenate(-2): a high yield route into Ru6C chemistry[1]

Autor:	Gerald B. Ansell, Ernestine W. Hill, John S. Bradley
Rok vydání:	1980
Předmět:	Carbon atom Organic Chemistry Diglyme Carbon-13 NMR Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Polymer chemistry Materials Chemistry Organic chemistry Molecule Physical and Theoretical Chemistry Derivative (chemistry) Carbon monoxide
Zdroj:	Journal of Organometallic Chemistry. 184:C33-C35
ISSN:	0022-328X
Popis:	Ru6C(CO)162- is produced in reproducibly high yield by the reduction of Ru312 with Mn(CO)5 in refluxing diglyme. 13C NMR evidence identifies carbon monoxide as the source of the encapsulated carbon atom. The facile prototype synthesis of an organometallic derivative of the Ru6C core is described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::172a5098c55570a40a46b3f3dac6bf89 https://doi.org/10.1016/s0022-328x(00)83498-1 Zobrazit plný text záznamu