Synthesis of doubly functionalized bis-tridentate ligands as building blocks for extended metallo-supramolecular assemblies and polymers
| Autor: | Christian H. Weidl, Jean-Marie Lehn, Ulrich S. Schubert |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Pyrimidine Ligand General Chemical Engineering Supramolecular chemistry chemistry.chemical_element General Chemistry Polymer Zinc Combinatorial chemistry Stille reaction chemistry.chemical_compound chemistry Pyridine Materials Chemistry Organic chemistry Cobalt |
| Zdroj: | Designed Monomers and Polymers. 2:1-17 |
| ISSN: | 1568-5551 |
| DOI: | 10.1163/156855599x00250 |
| Popis: | Doubly functionalized 4,6-bis(6-(2,2'-bipyridyl))pyrimidine ligands based on pyridine and pyrimidine units were synthesized starting from a commercially available nicotinic acid derivative using Stille-type carbon_carbon bond-forming reactions. The resulting hydroxy-terminated ligand, functionalized at the terminal pyridines, opens new avenues for the construction of extended metallo-supramolecular assemblies and polymers with novel material properties. Recent investigations of the synthesis and properties of the corresponding unsubstituted ligands showed the self-assembly of these ligands in the presence of metal ions such as cobalt(II) or zinc(II) to highly ordered tetranuclear [2 x 2]-grid-like architectures with novel magnetic and redox properties. |
| Databáze: | OpenAIRE |
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