A new FTIR method to monitor transesterification in biodiesel production by ultrasonication

Autor: Inmaculada Ramirez Uceda, Adrián Saiz Bermejo, D. Reyman, Miguel Rodriguez Gamero
Rok vydání: 2013
Předmět:
Zdroj: Environmental Chemistry Letters. 12:235-240
ISSN: 1610-3661
1610-3653
DOI: 10.1007/s10311-013-0440-4
Popis: New renewable fuels are urgently needed due to increasing fossil fuel pollution. Biodiesel, which contains alkyl esters produced by transesterification of oils, is an alternative fuel. Nevertheless, the main problem of biodiesel is its high price. Costs can be reduced by replacement of the current homogeneous catalysts by heterogeneous catalysts; however, research for new catalysts is actually slowed by lengthy analytical techniques. Here, we set up a simple and rapid analytical method using Fourier transform infrared (FTIR) to monitor transesterification. Conversion of sunflower and recycled cooking oils to their corresponding methyl esters was easily measured using a linear correlation between the intensity of an infrared peak at 1,437 cm−1 and the percent conversion. The results obtained by infrared were validated by gas chromatography. We also studied the effect of 20 kHz ultrasonic irradiation on biodiesel synthesis. Using our FTIR method, we found that replacing mechanical stirring with an ultrasonic probe leads to quality biodiesel in 10 min for sunflower oil and 20 min for recycled cooking oil.
Databáze: OpenAIRE
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