Reactions of alkoxyaluminium dichlorides with methylaluminium dichloride

Autor:	M. Boleslawski, Stanisław Pasynkiewicz, W. Kosińska, K. Z̵ardecka, A. Kunicki
Rok vydání:	1978
Předmět:	Inorganic Chemistry Reaction mechanism chemistry.chemical_compound Chemistry Group (periodic table) Organic Chemistry Materials Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Biochemistry Medicinal chemistry Aluminoxane
Zdroj:	Journal of Organometallic Chemistry. 153:281-288
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)92050-3
Popis:	Reactions of alkoxyaluminium compounds of the type ROAlCl 2 (R =Me, Et, n-Pr, i-Pr, n-Bu, t-Bu) with MeAlCl 2 were investigated. They proceed with the evolution of gases and the formation of aluminoxane systems AlOAl. The reaction products were identified by GC, IR and MS. The reaction mechanism is discussed. The influence of the type of OR group on the reactivity of alkoxyaluminium compounds was observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::16e6cedf2308fe4d1150c5cad236f0a3 https://doi.org/10.1016/s0022-328x(00)92050-3 Zobrazit plný text záznamu