Syn-gas from waste: the reduction of CO2 with H2S
Autor: | Ilia Korobkov, Peneau Virginie, Balamurugan Vidjayacoumar, Nicholas P. Alderman, Sandro Gambarotta, Camilo J. Viasus, Khalid Al-Bahily |
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Rok vydání: | 2019 |
Předmět: |
Fluid Flow and Transfer Processes
chemistry.chemical_classification Materials science Sulfide 020209 energy Process Chemistry and Technology 02 engineering and technology 021001 nanoscience & nanotechnology Catalysis Reduction (complexity) Metal Chemical engineering chemistry Chemistry (miscellaneous) visual_art 0202 electrical engineering electronic engineering information engineering visual_art.visual_art_medium Chemical Engineering (miscellaneous) 0210 nano-technology Syngas |
Zdroj: | Reaction Chemistry & Engineering. 4:763-771 |
ISSN: | 2058-9883 |
DOI: | 10.1039/c8re00334c |
Popis: | In this paper, we demonstrate that syngas (H2/CO) can be produced from oil waste (H2S/CO2) forming SO2 and S as secondary products at 600–800 °C in a flow reactor set-up. Numerous different metal sulfide catalysts have been tested for activity, with FeS and NiS appearing to be the most active. In both cases, the catalyst remains active after 120 hours online. X-ray diffraction confirmed that the catalyst remains under the form of the metal sulfide. |
Databáze: | OpenAIRE |
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