Interaction of Organonitriles with Electron Rich Calix[4]arene Derivatives on Gold Substrates

Autor:	Wan-Sang Kim, Geewon Chung, Dong-Myung Shin
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Stereochemistry Self-assembled monolayer General Chemistry Electron Condensed Matter Physics chemistry Polymer chemistry Thiol Molecule General Materials Science Gold surface Surface plasmon resonance Alkyl
Zdroj:	Molecular Crystals and Liquid Crystals. 464:93/[675]-101/[683]
ISSN:	1563-5287 1542-1406
DOI:	10.1080/15421400601030407
Popis:	We synthesized 25,26,27,28-tetrakis(mercaptobuthoxy)-5,11,17,23-[2,2′-thioxy(o-phenylene)thioxy-piperidino]calix[4]arene [1], 25,26,27,28-tetrakis(mercaptobuthoxy)-5,11,17,23-[2,2′-thioxy(o-phenylene)thioxy-amino]calix[4]arene [2] and 25,26,27,28-tetrakis(mercaptobuthoxy)-5,11,17,23-[2,2′-thioxy(o-phenylene)thioxy-aminopyrene] calix[4]arene [3] containing four alkyl thiol linkages, which allow the calix[4]arene to attach on the gold surface. We observed the binding of calix[4]arene derivatives and aromatic molecules with surface plasmon resonance and confirmed complexation of aromatic nitriles on calix[4]arene derivatives with FT-IR peak.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::16b6a81a036689ed023d4a135d5c7e51 https://doi.org/10.1080/15421400601030407 Zobrazit plný text záznamu