Out-of-plane chain interactions in dichlorobis(pyridine)copper(II) and dibromobis(pyridine)copper(II)

Autor: William E. Hatfield, David Y. Jeter
Rok vydání: 1972
Předmět:
Zdroj: Journal of Inorganic and Nuclear Chemistry. 34:3055-3060
ISSN: 0022-1902
DOI: 10.1016/0022-1902(72)80101-5
Popis: The magnetic susceptibilities of powdered samples of Cu(pyridine)2Cl2 and Cu(pyridine)2Br2 have been measured in the temperature range 8–297°K. The data reflect an antiferromagnetic interaction with Tmax near 18° for the chlorocomplex and near 36°K for the bromocomplex. The data are discussed in terms of the Heisenberg and Ising models of antiferromagnetic interactions in chains.
Databáze: OpenAIRE