ChemInform Abstract: Stereocontrolled Catalytic Asymmetric Reduction of Ketones with Oxazaborolidines Derived from New Chiral Amino Alcohols

Autor:	Yong Hae Kim, I. K. Yoon, Doo Han Park, C. S. Park, Il Suk Byun
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Enantioselective synthesis Organic chemistry General Medicine Borane Diphenylmethane derivatives Catalysis
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199350119
Popis:	The highly stereocontrolled enantioselective reduction of ketones in the presence of catalytic amounts of new chiral (S)-β-amino alcohols 1 and 2 with borane in THF at-78 o C process in high chemical and optical yields; secondary alcohols with the R-configuration are obtained in the presence of 1b, but secondary alcohols with the S-configuration are obtained in the presence of 2a
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::164f74478740d6b836c6061243fce690 https://doi.org/10.1002/chin.199350119 Zobrazit plný text záznamu Plný text