Complexes of cobalt(II), nickel(II) and copper(II) with 3,5-dimethylisoxazole as ligand

Autor:	G. Ponticelli, G. Devoto, C. Preti
Rok vydání:	1975
Předmět:	Denticity Polymers and Plastics Chemistry Ligand Inorganic chemistry chemistry.chemical_element Bridging ligand Magnetic susceptibility Copper Nickel Crystallography Octahedron Materials Chemistry Cobalt
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 37:1635-1639
ISSN:	0022-1902
DOI:	10.1016/0022-1902(75)80289-2
Popis:	The complexes of copper(II), nickel(II) and cobalt(II) with 3,5-dimethylisoxazole (3,5-diMeisox), have been prepared and studied by means of magnetic susceptibility measurements, infrared and far i.r. spectra, electronic spectroscopy and conductivity measurements. A copper(I) complex of the type Cu2(3,5-diMeisox)Br2 has been also obtained. The ligand behaves both as monodentate N-bonded, and as a bridging ligand N- and O-bonded. All the compounds here reported have an octahedral stereochemistry, except [Co(3,5-diMeisox)2X2] (X Cl, Br, I) which are tetrahedral and [Cu(3,5-diMeisox)4](ClO4)2 which is square planar.
Databáze:	OpenAIRE
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