Synthesis and characterization of structural and optical properties of heteroepitaxial brookite TiO2 single crystalline films
| Autor: | Mingxian Wang, Wei Zhao, Haisheng Xu, Weiguang Wang, Xuejian Du, Xianjin Feng, Jin Ma, Zhao Li |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Diffraction
Materials science 02 engineering and technology Substrate (electronics) Chemical vapor deposition 010402 general chemistry Epitaxy 01 natural sciences chemistry.chemical_compound General Materials Science High-resolution transmission electron microscopy Brookite Mechanical Engineering Metals and Alloys 021001 nanoscience & nanotechnology Condensed Matter Physics Microstructure 0104 chemical sciences Crystallography chemistry Chemical engineering Mechanics of Materials visual_art Titanium dioxide visual_art.visual_art_medium 0210 nano-technology |
| Zdroj: | Scripta Materialia. 115:75-79 |
| ISSN: | 1359-6462 |
| Popis: | Brookite titanium dioxide (b-TiO2) films were successfully deposited on Y-stabilized ZrO2 (110) substrates at different substrate temperatures (500–650 °C) by the metal organic chemical vapor deposition technique. The results of X-ray diffraction θ-2θ scan indicated that the b-TiO2 film deposited at 550 °C had the best single crystalline quality, for which the heteroepitaxial relationship and the microstructure were identified by the X-ray diffraction Φ scan and high resolution transmission electron microscopy measurements. A schematic diagram was proposed to clarify the epitaxial growth mechanism. The composition, morphology and optical properties of the b-TiO2 films have been investigated in detail. |
| Databáze: | OpenAIRE |
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