Synthesis and inhibitive characteristic of two acryloyl chloride derivatives towards the corrosion of API 5L X52 carbon steel in hydrochloric acid medium

Autor: Abd El-Aziz S. Fouda, Eid M. Khalil, Gamal A. EL-Mahdy, Ahmed S. Mohammed, Noureldin A. Abd El-Sattar
Rok vydání: 2022
Předmět:
Zdroj: Zeitschrift für Physikalische Chemie. 236:535-559
ISSN: 2196-7156
0942-9352
DOI: 10.1515/zpch-2021-3170
Popis: Two new organic based corrosion compounds were prepared from Acryloyl chloride are namely: N,N-bis(2-hydroxyethyl) acrylamide (DEA) and N-(2-hydroxyethyl) acrylamide (MEA). The prepared compounds were studied as corrosion inhibitors for carbon steel (CS) in 1 M hydrochloric acid solution while the efficiency of the prepared compounds were studied through different chemical (weight loss, WL) and electrochemical techniques [potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS)] in addition to, the theoretical techniques as Quantum chemical calculations, Monte Carlo simulation and the surface morphology study using atomic force microscopy (AFM). The obtained results showed that the investigated compounds are working as good corrosion inhibitors, the inhibition efficacy (%IE) increases with the increase of the compound concentrations. However, the %IE decreases with the rise in the temperature proving that the adsorption of the inhibitor molecules on the CS surface is physisorption, while the polarization data revealed that these compounds are classified as mixed kind inhibitors, that inhibits both anodic and cathodic reactions. Results reveal that DEA and MEA exhibit an excellent %IE of 89.2 and 71.6% at 60 ppm for DEA and MEA, respectively. The adsorption of the inhibitor molecules on CS surface following Langmuir adsorption isotherm. There is a strong matching between results obtained from experimental and theoretical studies. The order of the investigated inhibitors based on the %IE is DEA > MEA.
Databáze: OpenAIRE
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