Synthesis of Phenyl Dithiocarbamates Starting from Sodium Dialkyldithiocarbamates and Aryl Boronic Acids: a Copper Catalyzed S -Arylation

Autor:	Wan Xu, Shi-Bo Zhang, Ming-Yuan Gao, Yue-Sheng Li, Zhi-Bing Dong
Rok vydání:	2018
Předmět:	010405 organic chemistry Chemistry Sodium Aryl Organic Chemistry chemistry.chemical_element Substrate (chemistry) 010402 general chemistry 01 natural sciences Copper Combinatorial chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound Bromide Copper catalyzed Physical and Theoretical Chemistry
Zdroj:	European Journal of Organic Chemistry. 2018:6693-6698
ISSN:	1434-193X
DOI:	10.1002/ejoc.201801271
Popis:	A convenient and efficient protocol for the S-arylation of sodium dialkyldithiocarbamates was developed. With the catalysis of copper(I) bromide, sodium dialkyldithiocarbamates coupled with aryl boronic acids giving the C-S coupling products smoothly in good to excellent yields. This protocol features easily available starting materials, easy performance, short reaction time, broad substrate scope and good yields, showing its potential synthetic value for the convenient preparation of some potentially biologically active compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15d3ec3ecb8cd958c6b7b2b3c62ffcc5 https://doi.org/10.1002/ejoc.201801271 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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