| Autor: |
S. S. Vesely, I. A. Arkhipushkin, L. P. Kazansky, Yu. E. Pronin |
| Rok vydání: |
2014 |
| Předmět: |
|
| Zdroj: |
International Journal of Corrosion and Scale Inhibition. 3:078-088 |
| ISSN: |
2305-6894 |
| Popis: |
The electrochemical behavior of copper and zinc in neutral (рН 7.4) borate buffer solution with addition of 0.5 M NaCl and the effect of 2-merсaptobenzothiazole (MBT) on the electrochemical processes and adsorption on these metals has been studied by means of electrochemistry and X-ray photoelectron spectroscopy (XPS). The formation of MBT– metal cation complex films on copper and zinc surface has been shown. The effect of corrosive media composition and time-dependent relations of nanoscale film growth on the surface of the metals investigated have been determined. It was assumed that adsorbed MBT anion forms M(MBT)х, a polymeric complex where M = Cu + (x = 1) or Zn 2+ (x = 2). |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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