Step-by-step: uncommon SCSC transformation accompanied by stepwise change in the binding of a particular ligand within a mononuclear complex upon stepwise desolvation

Autor:	Pavel S. Koroteev, Andrey B. Ilyukhin, Andrey V. Gavrikov
Rok vydání:	2020
Předmět:	Crystallography chemistry.chemical_compound Transformation (genetics) Chemistry Ligand Phase (matter) Molecule General Materials Science Desolvation General Chemistry Carboxylate Condensed Matter Physics
Zdroj:	CrystEngComm. 22:2895-2899
ISSN:	1466-8033
DOI:	10.1039/d0ce00379d
Popis:	Herein, uncommon SCSC transitions within a mononuclear complex when desolvation provokes subtle changes in the molecular structure without alteration in nuclearity are reported. Namely, the stepwise κ1 → κ2 recoordination of a carboxylate ligand with an increase in CN from 7 to 8 was shown to occur through an unstable phase with a 7 + 1 coordination detected via an original technique.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15c7fdede41736553d1286846dadc963 https://doi.org/10.1039/d0ce00379d Zobrazit plný text záznamu