Stability of pentaammineosmium(II) in aqueous solution

Autor:	Karin A. Hughes, W. Dean Harman, Jason T. Call, M. G. Finn
Rok vydání:	1993
Předmět:	Reaction mechanism Aqueous solution Stereochemistry Reducing agent Medicinal chemistry Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Acetone Chemical stability Physical and Theoretical Chemistry Acetonitrile Chemical decomposition
Zdroj:	Inorganic Chemistry. 32:2123-2127
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00062a041
Popis:	The reduction of Os(NH 3 ) 5 (OTf) 3 in D 2 O or H 2 O over zinc amalgam gives rise to a species that retains the ability to form (NH 3 ) 5 Os 11 adducts with the π-acidic ligands acetone, N,N-dimethyluracil (DMU), and acetonitrile for periods of hours in the absence of reducing agent. The η 2 -DMU complex was shown not to be in equilibrium with free DMU, in contrast to a previous report.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15b8d7341bc7e9824a4cda5e4ada24e2 https://doi.org/10.1021/ic00062a041 Zobrazit plný text záznamu