Photochemische Cycloadditionen von 3-Phenyl-2H-azirinen mit Triphenyl-vinylphosphoniumbromid. 36. Mitteilung über Photoreaktionen

Autor:	Hans Schmid, Heinz Heimgartner, Nikolas Gakis
Rok vydání:	1974
Předmět:	Chemistry Organic Chemistry Phosphonium salt Biochemistry Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Bromide Yield (chemistry) Drug Discovery Organic chemistry Phosphonium Physical and Theoretical Chemistry Acetonitrile
Zdroj:	Helvetica Chimica Acta. 57:1403-1407
ISSN:	0018-019X
Popis:	On irradiation in acetonitrile 3-phenyl-2H-azirines of type 1 react with triphenyl vinyl phosphonium bromide to form in approximative 50% yield 2H-indoles of type 4 (Scheme 7). In analogy to other photochemical reactions with 2H-azirines [2] [3] it is assumed that the photochemically generated dipoles 2 react with the triphenyl vinyl phosphonium salt (Scheme 1). The conversion of 1 to 4 represents a new synthesis for 2H-pyrroles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15adb5e225fc6cb802d0004799c13a52 https://doi.org/10.1002/hlca.19740570516 Zobrazit plný text záznamu Plný text