Synthesis and Characterization of a New Imidazole Ligand and its Complexes with Cobalt(II), Nickel(II) and Copper(II)
| Autor: | Ulvi Avciata, I˙brahim Erden, Nebahat Demirhan |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Ligand Phenanthroline Inorganic chemistry chemistry.chemical_element Copper Inorganic Chemistry Metal chemistry.chemical_compound Nickel chemistry visual_art Polymer chemistry visual_art.visual_art_medium Imidazole Physical and Theoretical Chemistry Cobalt Crown ether |
| Zdroj: | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 36:559-562 |
| ISSN: | 1553-3182 1553-3174 |
| DOI: | 10.1080/15533170600862762 |
| Popis: | A new imidazole ligand, benzo[15‐crown‐5]‐1H‐imidazol[4,5‐f][1,10]phenanthroline (bip) has been synthesized from the reaction of 5,6‐diamino‐1,10‐phenanthroline with 4′‐formylbenzo‐15‐crown‐5. The Co(II), Ni(II) and Cu(II) complexes of the ligand were prepared and characterized. The metal to the ligand ratio of the Co(II), Ni(II) and Cu(II) complexes was found to be 2:1. The ligand and complexes have been characterized by FTIR, UV‐visible, 1H NMR, fluorescence spectrophotometer, elemental analyses and mass spectra. |
| Databáze: | OpenAIRE |
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